The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Organic radicals / CH3OC(O)OCH2 / Bilde(1997)_296K_240-300nm

DATAFILE: CH3OC(O)OCH2_Bilde(1997)_296K_240-300nm.txt
NAME: alkyl radical of dimethyl carbonate CH3O(O)OCH3
FORMULA: CH3OC(O)OCH2
AUTHOR(YEAR): Bilde(1997)
T: 296K
λ: 240-300nm
BIBLIOGRAPHY: M. Bilde, T.E. Møgelberg, J. Sehested, O.J. Nielsen, T.J. Wallington, M.D. Hurley, S.M. Japar, M. Dill, V.L. Orkin, T.J. Buckley, R.E. Huie, and M.J. Kurylo, "Atmospheric chemistry of dimethyl carbonate: Reaction with OH radicals, UV spectra of CH3OC(O)OCH2 and CH3OC(O)OCH2O2 radicals, reactions of CH3OC(O)OCH2O2 with NO and NO2, fate of CH3OC(O)OCH2O radicals", J. Phys. Chem. A 101, 3514-3525 (1997); DOI: 10.1021/jp961664r
COMMENTS: Reaction of OH radicals with dimethyl carbonate: pulse radiolysis/transient UV absorption techniques used to study the ultraviolet absorption spectrum of the transient reaction products CH3OC(O)OCH2 and CH3OC(O)CH2O2 at 296 K

Absorption cross sections as listed in Table 2

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